D. Datta et Dr. Beck, POSSIBILITY OF FORMATION OF RARE-EARTH NEGATIVE-IONS BY ATTACHMENT OFF ELECTRONS TO THE ATOMIC GROUND-STATE, Physical review. A, 47(6), 1993, pp. 5198-5201
Some recent experiments indicate that certain rare-earth negative ions
exist. Some local-density calculations indicate that attachment of f
electrons is most favorable for Tm and Md. Here we investigate by mean
s of relativistic configuration-interaction methods whether Tm- 4f14 a
nd Md- 5f14 are bound. Our results strongly suggest that they are not,
and that a different attachment process (perhaps that of a p electron
, as recently proposed by Vosko and Chevary [Bull. Am. Phys. Soc. 37,
1089 (1992)]) must be contemplated.