PHOTOTRANSPOSITION CHEMISTRY OF METHYLISOTHIAZOLES AND METHYLTHIAZOLES

Authors
PAVLIK JW PANDIT CR SAMUEL CJ DAY AC
Citation
Jw. Pavlik et al., PHOTOTRANSPOSITION CHEMISTRY OF METHYLISOTHIAZOLES AND METHYLTHIAZOLES, Journal of organic chemistry, 58(12), 1993, pp. 3407-3410
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
12
Year of publication
1993
Pages
3407 - 3410
Database
ISI
SICI code
0022-3263(1993)58:12<3407:PCOMAM>2.0.ZU;2-X
Abstract
Methylisothiazoles undergo phototransposition in neutral solution to m ethylthiazoles by a single permutation process. Methylisothiazole --> methylisothiazole transpositions, previously reported to occur, were n ot detected in these reactions. In trifluoroacetic acid solvent, proto nated methylisothiazoles and methylthiazoles phototranspose by P4 and P5 permutation pathways, respectively, resulting in a unique phototran sposition cycle.