ENANTIOPURE ENYNYL SULFOXIDES VIA PALLADIUM-CATALYZED COUPLING REACTIONS

Authors
PALEY RS LAFONTAINE JA VENTURA MP
Citation
Rs. Paley et al., ENANTIOPURE ENYNYL SULFOXIDES VIA PALLADIUM-CATALYZED COUPLING REACTIONS, Tetrahedron letters, 34(23), 1993, pp. 3663-3666
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
23
Year of publication
1993
Pages
3663 - 3666
Database
ISI
SICI code
0040-4039(1993)34:23<3663:EESVPC>2.0.ZU;2-I
Abstract
Enantiomerically pure 1-sulfinyl-1-en-3-ynes are prepared from 2-halov inylsulfoxides via Sonogashira or Stille coupling procedures. The tran s-enynyl sulfoxides may be hydrogenated to provide (1E, 3Z)-dienylsulf oxides.