REACTIONS OF ALPHA-EPOXYSILANES WITH ORGANOCOPPER REAGENTS - A STEREOSELECTIVE ROUTE TO ALKENES

Authors
CHAURET DC CHONG JM
Citation
Dc. Chauret et Jm. Chong, REACTIONS OF ALPHA-EPOXYSILANES WITH ORGANOCOPPER REAGENTS - A STEREOSELECTIVE ROUTE TO ALKENES, Tetrahedron letters, 34(23), 1993, pp. 3695-3698
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
23
Year of publication
1993
Pages
3695 - 3698
Database
ISI
SICI code
0040-4039(1993)34:23<3695:ROAWOR>2.0.ZU;2-9
Abstract
Reactions of alpha-epoxysilanes with cuprate reagents can be controlle d to give beta-silyl alcohols as major products. An oxidation, Grignar d addition, and elimination sequence then provides alkenes with up to 98% de.