ELECTRON-IMPACT DISSOCIATION OF NITROGEN

Authors
Citation
Pc. Cosby, ELECTRON-IMPACT DISSOCIATION OF NITROGEN, The Journal of chemical physics, 98(12), 1993, pp. 9544-9553
Citations number
50
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
98
Issue
12
Year of publication
1993
Pages
9544 - 9553
Database
ISI
SICI code
0021-9606(1993)98:12<9544:EDON>2.0.ZU;2-X
Abstract
The electron-impact dissociation of N2 to form two nitrogen atoms is o bserved in a crossed beam experiment at electron energies between 18.5 and 148.5 eV. Detection Of the correlated dissociation fragments with a time and position sensitive detector permits detection Of both grou nd and excited state fragments, but excludes interference from dissoci ative ionization products. The observed translational energy releases in the N2 dissociation are consistent with predissociation to N (2D) N (4S) fragments as the primary dissociation mechanism. Absolute cros s sections for the electron impact dissociation are measured and compa red with previous measurements. Recommended values of this cross secti on are given for electron-impact energies between 10 and 200 eV.