Jc. Greenwood et al., A STUDY OF THE CHEMICAL-COMPOSITION OF SOME COBALT SILICIDE LAYER STRUCTURES, Surface and interface analysis, 20(6), 1993, pp. 524-530
Auger and loss spectra and images have been obtained from a CoSi2 stan
dard and a structure containing cobalt-silicon films between a Co surf
ace layer and a silicon substrate. The results from a Phi 590 spectrom
eter and the York MULSAM instrument have been compared. Quantitative a
nalysis of the compositions of both samples has shown that elements ca
n be used as standards along with well-established matrix correction p
rocedures. However, the effects of preferential sputtering in conventi
onal depth profiling or bevel sectioning with ions lead to a complex c
omposition distribution that is depleted in Si at the surface. The pla
smon loss below the Co LVV Auger peak is enhanced in height near to th
e Si/silicide interface. The layer structure appears to be close to Co
/Co2Si/CoSi/Si.