CHARGE-TRANSFER FROM POLY(P-PHENYLENE VINYLENE) INTO MOLECULARLY DOPED POLYMER

Authors
ANTONIADIS H HSIEH BR ABKOWITZ MA STOLKA M
Citation
H. Antoniadis et al., CHARGE-TRANSFER FROM POLY(P-PHENYLENE VINYLENE) INTO MOLECULARLY DOPED POLYMER, Applied physics letters, 62(24), 1993, pp. 3167-3169
Citations number
24
Categorie Soggetti
Physics, Applied
Journal title
Applied physics letters → ACNP
ISSN journal
00036951
Volume
62
Issue
24
Year of publication
1993
Pages
3167 - 3169
Database
ISI
SICI code
0003-6951(1993)62:24<3167:CFPVIM>2.0.ZU;2-7
Abstract
We describe photoinduced charge transfer process in a bilayer device c omprised of poly(p-phenylene vinylene) (PPV) layer and a trap-free mol ecularly doped polymer containing diaryldiamine (TPD) dispersed in pol ycarbonate (PC). The time resolved charge transfer from PPV to TPD:PC in the presence of an electric field is analyzed. The injection (trans fer) efficiency of the photoinduced holes from PPV into TPD:PC is abou t 25% holes/photons at electric fields at 4 X 10(5) V/cm or higher. Mi nimal trapping of photocarriers at the interface region between the tw o polymer layers is associated with this transfer.