ELECTRON-DEFICIENT VANADIUM ALKYL COMPLEXES - SYNTHESIS AND MOLECULAR-STRUCTURE OF THE VANADIUM(III) DINITROGEN COMPLEX [(ME3CCH2)3V]2(MU-N2)

Authors
BUIJINK JKF MEETSMA A TEUBEN JH
Citation
Jkf. Buijink et al., ELECTRON-DEFICIENT VANADIUM ALKYL COMPLEXES - SYNTHESIS AND MOLECULAR-STRUCTURE OF THE VANADIUM(III) DINITROGEN COMPLEX [(ME3CCH2)3V]2(MU-N2), Organometallics, 12(6), 1993, pp. 2004-2005
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
6
Year of publication
1993
Pages
2004 - 2005
Database
ISI
SICI code
0276-7333(1993)12:6<2004:EVAC-S>2.0.ZU;2-Q
Abstract
The vanadium(III) dinitrogen-bridged complex [(Me3CCH2)3V]2(mu-N2) (1) , obtained from reaction Of VCl3(THF)3 and Me3CCH2Li under nitrogen, i s converted to the vanadium(V) oxo complex OV(CH2CMe3)3 (3) by reactio n with styrene oxide. Both 1 and 3 decompose at ambient temperature to give neopentane and species which are active in the ring-opening meta thesis polymerization of norbornene.