YLIDE GOLD(I) COMPLEXES OF THE TYPES [AU(YLIDE)L]+, [AU(YLIDE)(CCR)] AND [AU(YLIDE)(CO(CO)4)]

Authors
AGUIRRE CJ GIMENO MC LAGUNA A LAGUNA M DELUZURIAGA JML PUENTE F
Citation
Cj. Aguirre et al., YLIDE GOLD(I) COMPLEXES OF THE TYPES [AU(YLIDE)L]+, [AU(YLIDE)(CCR)] AND [AU(YLIDE)(CO(CO)4)], Inorganica Chimica Acta, 208(1), 1993, pp. 31-36
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
208
Issue
1
Year of publication
1993
Pages
31 - 36
Database
ISI
SICI code
0020-1693(1993)208:1<31:YGCOTT>2.0.ZU;2-J
Abstract
Displacement of tetrahydrothiophene (tht) from [Au(ylide)(tht)ClO4 (yl ide=CH2PPh3, CH2PPh2Me, CH2PPhMe2, CHPhPPh3, CHMePPh3 or CH2AsPh3) by other neutral or anionic ligands leads to the mono- and dinuclear cati onic complexes [Au(ylide)L]ClO4 (L=SbPh3 or phen) or [{Au(ylide)}2(L-L )]ClO4 (L-L=dppm or dpam), complexes with tetracarbonylcobaltate as li gand [Au(ylide){Co(CO)4}] or acetylide complexes [Au(ylide)(C=CR)] (R= Ph or (t)Bu). The structure of [Au(CH2PPhMe2)(phen)]ClO4 was establish ed by single-crystal X-ray diffraction studies.