Id. Rubin et Mm. Kapuscinski, VISCOSITIES OF ETHYLENE-PROPYLENE DIENE TERPOLYMER BLENDS IN OIL, Journal of applied polymer science, 49(1), 1993, pp. 111-115
Viscosities were obtained on oil solutions of two ethylene-propylene-d
iene terpolymers (EPDMs) and their blends. For the amorphous terpolyme
r with 59 mol % ethylene, intrinsic viscosities were constant between
-10 and 40-degrees-C. The viscosities decreased rapidly at low tempera
ture for blends of this material with as little as 20 wt % of a slight
ly crystalline EPDM with 79 mol % ethylene. Dynamic viscosity measurem
ents on 1.0% solutions of blends likewise gave considerably smaller va
lues at low temperature than measurements on an amorphous EPDM of simi
lar molecular weight. The data are in agreement with the view that lon
ger ethylene sequences that crystallize in the bulk polymer can organi
ze in oil into ordered domains that interfere less with flow than the
disordered amorphous polymer regions.