DIFFERENTIAL THERMAL-ANALYSIS UNDER PRESSURE ON CYANOCYCLOHEXANE, ,4-TETRAHYDRO-5,6-DIMETHYL-1,4-METHANONAPHTHALENE, AND 2-METHYL-2-PROPANOL

Citation
J. Reuter et al., DIFFERENTIAL THERMAL-ANALYSIS UNDER PRESSURE ON CYANOCYCLOHEXANE, ,4-TETRAHYDRO-5,6-DIMETHYL-1,4-METHANONAPHTHALENE, AND 2-METHYL-2-PROPANOL, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 48(5-6), 1993, pp. 705-708
Citations number
21
Categorie Soggetti
Chemistry Physical",Physics
ISSN journal
09320784
Volume
48
Issue
5-6
Year of publication
1993
Pages
705 - 708
Database
ISI
SICI code
0932-0784(1993)48:5-6<705:DTUPOC>2.0.ZU;2-D
Abstract
Differential thermal analysis has been performed on cyanocyclohexane ( CCH), 3,4-tetrahydro-5,6-dimethyl-1,4-methanonaphthalene (TDMN), and 2 -methyl-2-propanol (t-butanol) up to 300 MPa. The latter compound was also investigated dielectrically. CCH displays an ODIC phase that tran sforms only reluctantly to the low-temperature stable phase II. Anneal ing under pressure can appreciably accelerate this transformation. For all three compounds the phase diagrams were established. For CCH and TDMN also the pressure dependence of the glass transition has been det ermined.