SOLVATOCHROMIC FLUORESCENCE OF 8-(PHENYLAMINO)-1-NAPHTHALENE-AMMONIUMSULFONATE (8,1 ANS) IN 1,4-DIOXANE WATER MIXTURES, REVISITED

Authors
HUTTENHAIN SH BALZER W
Citation
Sh. Huttenhain et W. Balzer, SOLVATOCHROMIC FLUORESCENCE OF 8-(PHENYLAMINO)-1-NAPHTHALENE-AMMONIUMSULFONATE (8,1 ANS) IN 1,4-DIOXANE WATER MIXTURES, REVISITED, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 48(5-6), 1993, pp. 709-712
Citations number
20
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
48
Issue
5-6
Year of publication
1993
Pages
709 - 712
Database
ISI
SICI code
0932-0784(1993)48:5-6<709:SFO8>2.0.ZU;2-5
Abstract
The correlation of the solvatochromic fluorescence properties of 8-(ph enylamino)-1-naphthalene-ammoniumsulfonate (8,1 ANS) in 1,4-dioxane/wa ter mixtures with E(T)(30) and DELTAf values of the respective solvent s shows that besides the polarity the nature of the solvent mixture de termines the fluorescence intensity I and the Stokes shift DELTAnuBAR. Different amounts of hydrogen-bonding are suggested to be responsible for the different slopes of the correlation line plots.