INSITU OXIDATIVE-DEGRADATION OF FORMALDEHYDE WITH ELECTROGENERATED HYDROGEN-PEROXIDE

The factors affecting the cathodic reduction of oxygen to hydrogen per oxide and the degradation of formaldehyde using in situ generated hydr ogen peroxide are presented in this work. The current efficiency for t he production of hydrogen peroxide on graphite has been indicated by t he experimental results to have been significantly affected by the pH value, the current density, the temperature, and the oxygen sparging r ate. The maximum current efficiency for the cathodic reduction of oxyg en to hydrogen peroxide was 93.5%. The degradation of formaldehyde by the electrogenerated hydrogen peroxide was primarily governed by the c urrent density, the pH value, and the temperature. The degradation fra ction of formaldehyde was more than 99% whenever the initial concentra tion of formaldehyde was in the range of 250 to 1000 ppm.