H. Shih et al., ELECTROCHEMICAL MEASUREMENTS OF THE CORROSION BEHAVIOR OF TYPE 304LSSIN N2H4 CONTAINING CO2, Journal of the Electrochemical Society, 140(6), 1993, pp. 1661-1666
Electrochemical dc and ac methods were used to evaluate the corrosion
behavior of stainless steel 304L in hydrazine (N2H4) with or without a
dditions Of CO2. Tafel slopes and corrosion current densities were obt
ained from the analysis of polarization curves recorded in the vicinit
y of the corrosion potential after elimination of the ohmic drop. Elec
trochemical impedance spectroscopy was used to monitor the continuous
changes of the corrosion kinetics with increasing additions of CO2 in
N2H4. The results obtained with both techniques show that minute addit
ion (up to 100 PPM) Of CO2 increased the corrosion rate of the stainle
ss steel in N2H4. Further CO2 addition produced no additional changes.