INTRAMOLECULAR DIELS-ALDER REACTION OF VINYLSULFONATES POSSESSING AN ACYCLIC DIENE MOIETY

Citation
P. Metz et M. Fleischer, INTRAMOLECULAR DIELS-ALDER REACTION OF VINYLSULFONATES POSSESSING AN ACYCLIC DIENE MOIETY, Synlett, (6), 1993, pp. 399-400
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
09365214
Issue
6
Year of publication
1993
Pages
399 - 400
Database
ISI
SICI code
0936-5214(1993):6<399:IDROVP>2.0.ZU;2-A
Abstract
Vinylsulfonates 2 possessing an acyclic diene moiety undergo intramole cular cycloaddition in refluxing toluene. The diastereoselectivity of this process is substantially enhanced if the diene substituent R2 is larger than hydrogen.