S. Toyoda et al., EVALUATION OF PROPERTIES OF ALUMINUM FILMS DEPOSITED USING AN ULTRAHIGH-VACUUM SPUTTERING SYSTEM, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 163(2), 1993, pp. 167-170
To explore the effects of residual impurity gases, such as H2O vapor a
nd N2 gas, in a sputtering environment on the crystallographic texture
and grain sizes of Al-1%Si films, a quantitative study was carried ou
t using an ultrahigh vacuum sputtering system. It was found that a sma
ll increase in the amount of H2O vapor in a sputtering environment red
uced the growth of Al-Si film toward a (111) texture and also suppress
ed grain growth. In contrast, the residual N2 gas had no influence on
the crystallographic texture of the Al-Si film up to an N2 partial pre
ssure of 1.2 x 10(-3) Pa. These results indicate that a bakeable ultra
high vacuum sputtering system with low-level residual H2O vapor is sui
table for producing reliable aluminum interconnects.