Scanning tunneling microscopy in liquid environment has gained an incr
eased interest in recent years. The specific features of the in situ o
bservation of surface structures at the solid/liquid interface are fir
st presented. Next, a high resolution imaging of high oriented pyrolyt
ic graphite (HOPG) graphite surface shows the potentiality of our home
-made microscope. The last study, performed on technological InP subst
rates, illustrates the extensive applications of in situ imaging in th
e fields of semiconductor technology.