The temperature of shock compressed iron has been measured to 340 GPa,
using well characterized iron films sputtered on transparent diamond
substrates and a 1 ns time-resolved optical method. We find a knee on
the (P,T) iron Hugoniot indicating melting at 6350 K and 235 GPa and a
t 6720 K and 300 GPa. An extrapolation yields an iron melting temperat
ure of 6830 (+/- 500) K at 330 GPa, the pressure of the Earth inner-ou
ter core boundary. Implication of the melting data for the iron phase
diagram is also discussed.