DIPOLE, QUADRUPOLE, OCTUPOLE, AND DIPOLE-DIPOLE QUADRUPOLE POLARIZABILITIES AND 2ND HYPERPOLARIZABILITIES AT REAL AND IMAGINARY FREQUENCIESFOR HELIUM IN THE 2(3)S STATE - DISPERSION ENERGY COEFFICIENTS FOR INTERACTIONS BETWEEN HE(2S-3) AND H(1S-2), HE(1S-1), HE(2S-3), OR H-2(X(1)SIGMA(G)+)

Authors
Citation
Dm. Bishop et J. Pipin, DIPOLE, QUADRUPOLE, OCTUPOLE, AND DIPOLE-DIPOLE QUADRUPOLE POLARIZABILITIES AND 2ND HYPERPOLARIZABILITIES AT REAL AND IMAGINARY FREQUENCIESFOR HELIUM IN THE 2(3)S STATE - DISPERSION ENERGY COEFFICIENTS FOR INTERACTIONS BETWEEN HE(2S-3) AND H(1S-2), HE(1S-1), HE(2S-3), OR H-2(X(1)SIGMA(G)+), International journal of quantum chemistry, 47(2), 1993, pp. 129-134
Citations number
15
Categorie Soggetti
Chemistry Physical
ISSN journal
00207608
Volume
47
Issue
2
Year of publication
1993
Pages
129 - 134
Database
ISI
SICI code
0020-7608(1993)47:2<129:DQOADQ>2.0.ZU;2-5
Abstract
We have determined the dynamic dipole (alpha1), quadrupole (alpha2), o ctupole (alpha3), and dipole-dipole-quadrupole (B) polarizabilities an d the second hyperpolarizability tensor (gamma) for the helium atom in its lowest triplet state (2(3)S). We have done so for both real and i maginary frequencies: in the former case, for a range of frequencies ( omega) between zero and the first electronic-transition frequency, and in the latter case for a 32-point Gauss-Legendre grid running from ze ro to HomegaBAR = 20 E(h). We have also determined the dispersion-ener gy coefficients C6, C-8, and C-10 for the systems (H(1S))-S-2-(He(2S)) -S-3, (He(1S))-S-1-(He(2S))-S-3, and (He(2)S))-S-3-(He(2S))-S-3 and C- 6(0), C-6(2), C-8(0), C-8(2) and C-8(4) coefficients for the interacti on (He(2S))-S-2-H-2(X1SIGMA(g)+). Our values of the higher-order multi polar polarizabilities and of gamma for the 2(3)S state of helium are, we believe, the first to be published.