REACTION OF BENZYL ALCOHOL OVER THE HYDROGEN STORAGE INTERMETALLIC COMPOUND MG2CU

Citation
R. Valarivan et al., REACTION OF BENZYL ALCOHOL OVER THE HYDROGEN STORAGE INTERMETALLIC COMPOUND MG2CU, Reaction kinetics and catalysis letters, 59(2), 1996, pp. 343-350
Citations number
14
Categorie Soggetti
Chemistry Physical
ISSN journal
01331736
Volume
59
Issue
2
Year of publication
1996
Pages
343 - 350
Database
ISI
SICI code
0133-1736(1996)59:2<343:ROBAOT>2.0.ZU;2-8
Abstract
The reaction of benzyl alcohol over the hydrogen storage intermetallic s Mg2Cu was studied in the temperature range of 573-773 K. Benzaldehyd e and toluene, the major products, were produced by dehydrogenation an d disproportionation reactions, respectively. Anthracene, stilbene and benzyltoluenes were also formed due to benzylation reaction. Since th e benzylation course was strongly influenced by shape selectivity cons iderations, these were produced in minor amounts. Below 673 Y Mg2Cu be haves like metals while above 673 K it behaves like oxide systems in i ts catalytic properties.