The content and distribution of lanthanum, cerium, samarium, and europ
ium in the main soil groups of the Volga Upland are studied. The main
factor responsible for the differentiation of these elements within a
single physiographic region is the lithogeochemistry of the parent mat
erial. All the examined elements participate in sorption and humus acc
umulation, and samarium and lanthanum are involved in eluvial-illuvial
redistribution. Soil formation leads to the convergence of these elem
ents in soils on different parent materials.