RHODIUM-MEDIATED 100-PERCENT REGIOSELECTIVE OXIDATIVE HYDROAMINATION OF ALPHA-OLEFINS

Authors
BRUNET JJ NEIBECKER D PHILIPPOT K
Citation
Jj. Brunet et al., RHODIUM-MEDIATED 100-PERCENT REGIOSELECTIVE OXIDATIVE HYDROAMINATION OF ALPHA-OLEFINS, Tetrahedron letters, 34(24), 1993, pp. 3877-3880
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
24
Year of publication
1993
Pages
3877 - 3880
Database
ISI
SICI code
0040-4039(1993)34:24<3877:R1ROHO>2.0.ZU;2-Q
Abstract
The system generated from lithium anilide and [(Et3P)2RhCl]2 catalyzes (turnover 21) the regioselective condensation of aniline with styrene to give a mixture of PhNH-CH(CH3)Ph (hydroamination product) and PhN= C(CH3)Ph (oxidative hydroamination product) in c.a.1/2 ratio. This 100 % regioselective oxidative hydroamination has been confirmed in the ca se of 1-hexene.