USE OF RE(C5H7O2)3 IN PREPARATION OF CATALYSTS FOR OLEFIN METATHESIS

Authors
KLIMOV OV KHOMYAKOVA EA STARTSEV AN
Citation
Ov. Klimov et al., USE OF RE(C5H7O2)3 IN PREPARATION OF CATALYSTS FOR OLEFIN METATHESIS, Catalysis letters, 19(2-3), 1993, pp. 189-195
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
19
Issue
2-3
Year of publication
1993
Pages
189 - 195
Database
ISI
SICI code
1011-372X(1993)19:2-3<189:UORIPO>2.0.ZU;2-1
Abstract
New catalysts for olefin metathesis are obtained upon interaction betw een rhenium trisacetylacetonate and Y-Al2O3 surface. After high temper ature treatment in flows Of O2 and N2 and addition of organometallic c ompound as a cocatalyst the activity of the resulting catalyst exceeds that of known Re/Al2O3 catalysts prepared by impregnation. The cataly sts exhibit maximal activity at a cocatalyst surface concentration of 3 x 10(-7) mol/m2. Further increase of the cocatalyst concentration le ads to deactivation.