The linearly polarized reflectance from a leaf depends on the characte
ristics of the leaf surface. In the present study the leaf reflectance
of a number of plant species with varying surface characteristics was
measured at the Brewster angle with a polarization photometer having
5 visible and near-infrared wavelength bands. We found that all leaf s
urfaces polarized incident light. Differences among species could be e
xplained by variation in surface features. The results support our hyp
othesis that the polarized light is reflected by the leaf surface, not
by its interior. Two mechanisms appeared responsible for the linearly
polarized reflectance: (1) specular reflectance and (2) surface parti
cle scattering. In most cases, large values of linearly polarized refl
ectance could be attributed to specular reflectance from the leaf surf
ace. Attribution required knowledge of the optical dimensions of featu
res on the leaf surface.