NEW ORGANIC METALS ET2[HG(SCN)CL2] AND ET2[HG(SCN)2CL]

Authors
ALDOSHINA MZ LYUBOVSKAYA RN KONOVALIKHIN SV DYACHENKO OA MAKOVA MK LYUBOVSKII RB
Citation
Mz. Aldoshina et al., NEW ORGANIC METALS ET2[HG(SCN)CL2] AND ET2[HG(SCN)2CL], Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 230, 1993, pp. 677-681
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
230
Year of publication
1993
Pages
677 - 681
Database
ISI
SICI code
1058-725X(1993)230:<677:NOMEAE>2.0.ZU;2-W
Abstract
New two-dimensional organic metals ET2[Hg(SCN)3-nXn], X=F,C1,Br,I have been synthesized and investigated. ET2[Hg(SCN)Cl2](I) and ET2[Hg(SCN) 2Cl](II) are isostructural. Cationic sheets of kappa-type alternate wi th anionic sheets. The anions [Hg(SCN)3-nCln]-(n=1,2) have a polymeric structure and form the chains with one or two bridge ligand SCN. Both salts have a metallic character of conductivity till 35 K (I) and 50 K (II), respectively, at lower temperatures they become insulators.