ADIABATICITY IN ELECTROCHEMICAL ELECTRON-TRANSFER - A PERSPECTIVE FROM A DIFFUSION-REACTION EQUATION APPROACH

Authors
SEBASTIAN KL CHAKRAVARTI N
Citation
Kl. Sebastian et N. Chakravarti, ADIABATICITY IN ELECTROCHEMICAL ELECTRON-TRANSFER - A PERSPECTIVE FROM A DIFFUSION-REACTION EQUATION APPROACH, Journal of electroanalytical chemistry [1992], 351(1-2), 1993, pp. 57-63
Citations number
14
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
351
Issue
1-2
Year of publication
1993
Pages
57 - 63
Database
ISI
SICI code
Abstract
A theoretical study of electrochemical electron transfer (ECET) using the diffusion-reaction equation approach is presented. The rate expres sion for the transfer of an electron from an ion in solution to the me tal electrode is derived. The concept of adiabaticity as applied to EC ET is looked into in the light of this approach.