ELECTROCHEMISTRY AND SPECTROELECTROCHEMISTRY OF SUBSTITUTED TETRABENZOTRIAZAPORPHINE

Authors
TSE YH GOEL A HU MG LEVER ABP LEZNOFF CC VANLIER JE
Citation
Yh. Tse et al., ELECTROCHEMISTRY AND SPECTROELECTROCHEMISTRY OF SUBSTITUTED TETRABENZOTRIAZAPORPHINE, Canadian journal of chemistry, 71(5), 1993, pp. 742-753
Citations number
44
Categorie Soggetti
Chemistry
Journal title
Canadian journal of chemistry → ACNP
ISSN journal
00084042
Volume
71
Issue
5
Year of publication
1993
Pages
742 - 753
Database
ISI
SICI code
0008-4042(1993)71:5<742:EASOST>2.0.ZU;2-W
Abstract
The spectral and electrochemical properties of tetrabenzo[5,10,15]tria zaporphine (TBTAP) and its magnesium derivatives having a long alkyl c hain attached to the meso carbon have been studied. Both metal-free an d metallated species show typical metal-free phthalocyanine-like spect ra. Two reduction and two oxidation redox couples have been observed. The cation, anion, and dianion species of these porphyrin derivatives have been electrochemically generated and their electronic spectra are recorded.