[MO3(IV)S(S2)6]2- FROM AMORPHOUS MOS3 BY THE REACTION WITH OH- AND R = 0.015 STRUCTURE OF (NH4)2[MO3(IV)S(S2)6].H2O

Authors
MULLER A DIEMANN E KRICKEMEYER E WALBERG HJ BOGGE H ARMATAGE A
Citation
A. Muller et al., [MO3(IV)S(S2)6]2- FROM AMORPHOUS MOS3 BY THE REACTION WITH OH- AND R = 0.015 STRUCTURE OF (NH4)2[MO3(IV)S(S2)6].H2O, European journal of solid state and inorganic chemistry, 30(5), 1993, pp. 565-572
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
30
Issue
5
Year of publication
1993
Pages
565 - 572
Database
ISI
SICI code
0992-4361(1993)30:5<565:[FAMBT>2.0.ZU;2-F
Abstract
A refined crystal structure determination (R=0.015) of (NH4)2 [Mo3S13] . H2O including H-atom positions of the NH4+ ions is reported. The fo rmation of the cluster anion [Mo3S13]2- from amorphous MoS3, suspended in O2- free aqueous ammonia solution at room temperature, is describe d. This observation is discussed in terms of triangular sulfide and di sulfide bridged Mo3 units regarded as structural features in the amorp hous educt.