Rl. Johnson et Lce. Taylor, DIFFERENCES IN THE KETO-ENOL EQUILIBRIUM OF [M-IMPACT AND FAST-ATOM-BOMBARDMENT IONIZATION(H]+ IONS OF BUPROPION FORMED BY ELECTRON), Organic mass spectrometry, 28(6), 1993, pp. 699-703
The fragmentation of the protonated molecular ion of bupropion produce
d by collisionally induced decomposition is shown to depend on the ion
ization method used to form the [ M + H ] + ion. 'The daughter ion pro
ducts do not depend on the energy of decomposition, i.e. high- or low-
energy collisions, but on the ratio of the keto-enol equilibrium as in
fluenced by the ionization process.