The optical functions of several forms of thin-film silicon (amorphous
Si, fine-grain polycrystalline Si, and large-grain polycrystalline Si
) grown on oxidized Si have been determined using 2-channel spectrosco
pic polarization modulation ellipsometry from 240 to 840 nm (approxima
tely 1.5-5.2 eV). It is shown that the standard technique for simulati
ng the optical functions of polycrystalline silicon (an effective medi
um consisting of crystalline Si, amorphous Si, and voids) does not fit
the ellipsometry data.