ELECTROSYNTHESES OF DISACCHARIDES FROM PHENYL OR ETHYL 1-THIOGLYCOSIDES

Authors
MALLET JM MEYER G YVELIN F JUTAND A AMATORE C SINAY P
Citation
Jm. Mallet et al., ELECTROSYNTHESES OF DISACCHARIDES FROM PHENYL OR ETHYL 1-THIOGLYCOSIDES, Carbohydrate research, 244(2), 1993, pp. 237-246
Citations number
71
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Carbohydrate research → ACNP
ISSN journal
00086215
Volume
244
Issue
2
Year of publication
1993
Pages
237 - 246
Database
ISI
SICI code
0008-6215(1993)244:2<237:EODFPO>2.0.ZU;2-6
Abstract
Constant current electrolyses of the glycosyl donors phenyl and ethyl 3,4,6-tetra-O-benzyl-1-thio-beta-D-glucopyranoside in dry acetonitrile in the presence of various primary and secondary sugar alcohols, perf ormed in an undivided cell, gave beta-linked disaccharide derivatives selectively in good yields. Phenyl ,4,6-tetra-O-benzoyl-1-thio-beta-D- glucopyranoside gave the beta-glucosides exclusively in good to modera te yields.