PREPARATION OF MESO-TETRA(4-GALVINOLPHENYL)PORPHYRIN - A BUILDING-BLOCK FOR MOLECULAR MAGNETIC-MATERIALS

Authors
SHULTZ DA KNOX DA MORGAN LW SANDBERG K TEW GN
Citation
Da. Shultz et al., PREPARATION OF MESO-TETRA(4-GALVINOLPHENYL)PORPHYRIN - A BUILDING-BLOCK FOR MOLECULAR MAGNETIC-MATERIALS, Tetrahedron letters, 34(25), 1993, pp. 3975-3978
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
25
Year of publication
1993
Pages
3975 - 3978
Database
ISI
SICI code
0040-4039(1993)34:25<3975:POM-AB>2.0.ZU;2-9
Abstract
The synthesis and oxidative electrochemistry of a free-radical substit uted metalloporphyrin are described. The porphyrin is prepared in four steps in good yield. Oxidation at a platinum electrode shows the mole cule undergoes five reversible one-electron transfers to a stable pent aradical.