A NOVEL ROUTE TO N-SUBSTITUTED ALLYLAMINES BY THE REACTION OF ALLYLSILANES WITH (ETHOXYCARBONYL)NITRENE

Authors
FIORAVANTI S LORETO MA PELLACANI L RAIMONDI S TARDELLA PA
Citation
S. Fioravanti et al., A NOVEL ROUTE TO N-SUBSTITUTED ALLYLAMINES BY THE REACTION OF ALLYLSILANES WITH (ETHOXYCARBONYL)NITRENE, Tetrahedron letters, 34(25), 1993, pp. 4101-4104
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
25
Year of publication
1993
Pages
4101 - 4104
Database
ISI
SICI code
0040-4039(1993)34:25<4101:ANRTNA>2.0.ZU;2-Q
Abstract
The reaction of mono- and disubstituted allylsilanes with (ethoxycarbo nyl)nitrene allowed the preparation of the N-substituted allylamines 2 a, 2b, 2c and 2d in yields up to 60%. The 2-ethoxyoxazolines 3a, 3b an d 3c were isolated as minor products.