S. Dahm et al., PREPARATION AND PHYSICAL-PROPERTIES OF HIGHLY CONDUCTING METAL (M = NI, CO, CU) COORDINATION POLYMERS, Synthetic metals, 55(2-3), 1993, pp. 884-889
Coordination polymers of nickel, cobalt and copper with the linking po
lydentate ligands tetrathiafulvalenetetrathiolate, benzene-1,2,4,5-tet
rathiolate and phthalocyaninate have been prepared. The environmentall
y very stable materials have dc conductivities ranging between 10(-2)
S.cm-1 for the polyphthalocyaninato derivatives and 10(2) S.cm-1 for t
he tetrathiafulvalenetetrathiolates. The temperature dependence of the
dc conductivity of the latter compounds is remarkably low.