Mr. Andersson et al., SYNTHESIS OF SOLUBLE POLY(ALKYLTHIOPHENES) WHICH ARE THERMALLY STABLEIN THE DOPED STATE, Synthetic metals, 55(2-3), 1993, pp. 1227-1231
We have prepared poly(3-octyl-2,2'-bithiophene) and poly(3'-octyl-2,2'
;5'2''-terthiophene) and found that they show better stability against
thermal dedoping than poly(3-octylthiophene). A reduction of the numb
er of alkyl side chains in a regular way lead to better space for the
counter ion on doping, more planar pi-system and a more rigid polymer
backbone, compared to poly(3-octylthiophene).