SYNTHESIS AND CHARACTERIZATION OF NEW THIOPHENE - CONTAINING POLYAZOMETHINES

Authors
DUBITSKY YA CATELLANI M BOLOGNESI A DESTRI S PORZIO W
Citation
Ya. Dubitsky et al., SYNTHESIS AND CHARACTERIZATION OF NEW THIOPHENE - CONTAINING POLYAZOMETHINES, Synthetic metals, 55(2-3), 1993, pp. 1266-1271
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
55
Issue
2-3
Year of publication
1993
Pages
1266 - 1271
Database
ISI
SICI code
0379-6779(1993)55:2-3<1266:SACONT>2.0.ZU;2-J
Abstract
New thiophene-containing polyazomethines have been synthesized by chem ical polymerization in the presence of either copperII underbar perchl orate or its ammonia complex. The monomers were prepared by condensati on of 2-thiophenecarboxyaldehyde with aromatic diamines. The structure of both monomers and polymers has been studied by FT-IR, NMR, ESR and X-ray spectroscopies. The polymers, in oxidized form, contain from 0. 5 up to 2.0 perchlorate anions per unit dependending on the reaction c onditions and nature of oxidizing agent. Their electrical conductiviti es varied in the range 10(-2) - 10(-5) S/cm.