DERIVATIVES OF POLY(PYRROLE) WITH DECONJUGATED CARBONYL SUBSTITUENTS IN BETA-POSITION

Authors
VOIGT M GEISSLER U HAASE V VOIGT B HALLENSLEBEN ML TOPPARE L
Citation
M. Voigt et al., DERIVATIVES OF POLY(PYRROLE) WITH DECONJUGATED CARBONYL SUBSTITUENTS IN BETA-POSITION, Synthetic metals, 55(2-3), 1993, pp. 1441-1446
Citations number
14
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
55
Issue
2-3
Year of publication
1993
Pages
1441 - 1446
Database
ISI
SICI code
0379-6779(1993)55:2-3<1441:DOPWDC>2.0.ZU;2-P
Abstract
Four omega-(3-pyrrolyl)esters were investigated by cyclic voltammetry, electron microscopy and conductivity measurements. The corresponding poly(pyrrole) derivatives exhibit enhanced conductivities compared to poly(3-acylpyrrole)s, and their electrochemical behavior resembles tha t of poly(3-alkylpyrrole)s rather than the poly(3-acylpyrrole) derivat ives. Ester saponification occurring during electropolymerization was examined by gas chromatography.