SYNTHESIS AND THERMAL-DECOMPOSITION OF SUBSTITUTED [2-(ACYLOXY)ALKYL]DIORGANOTIN COMPOUNDS, BU2SN(X)CH2CHR1OCOR2(X = HALOGEN, 2,4-PENTANEDIONATE, OR OCOR), POTENTIAL SOURCES OF ORGANOTIN CATALYSTS

Authors
JOUSSEAUME B GUILLOU V NOIRET N PEREYRE M FRANCES JM
Citation
B. Jousseaume et al., SYNTHESIS AND THERMAL-DECOMPOSITION OF SUBSTITUTED [2-(ACYLOXY)ALKYL]DIORGANOTIN COMPOUNDS, BU2SN(X)CH2CHR1OCOR2(X = HALOGEN, 2,4-PENTANEDIONATE, OR OCOR), POTENTIAL SOURCES OF ORGANOTIN CATALYSTS, Journal of organometallic chemistry, 450(1-2), 1993, pp. 97-102
Citations number
44
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
450
Issue
1-2
Year of publication
1993
Pages
97 - 102
Database
ISI
SICI code
0022-328X(1993)450:1-2<97:SATOS[>2.0.ZU;2-Q
Abstract
Halido-, (2,4-pentadionato-O,O')- and (acyloxy)[2-(acyloxy)ethyl]dibut ylstannanes, Bu2Sn(X)CH2CHR1OCOR2 (X = halogen, 2,4-pentanedionate, or OCOR) have been prepared, either by hydrostannation of vinyl esters o r by condensation of stannyllithium compounds with epoxides followed b y esterification. These thermally-unstable compounds are easily decomp osed in diorganotin compounds with two heteroatom donors. Some are goo d catalyst sources for silicone curing and polyurethane preparation.