THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(INDAZOL-1-YL)PYRIDIN-2'-YLMETHANE (BIPM) AND [RH(BIPM)(NBD)]PF6

Authors
GALLEGOPRECIADO MCL BALLESTEROS P CLARAMUNT RM CANO M HERAS JV PINILLA E MONGE A
Citation
Mcl. Gallegopreciado et al., THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(INDAZOL-1-YL)PYRIDIN-2'-YLMETHANE (BIPM) AND [RH(BIPM)(NBD)]PF6, Journal of organometallic chemistry, 450(1-2), 1993, pp. 237-244
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
450
Issue
1-2
Year of publication
1993
Pages
237 - 244
Database
ISI
SICI code
0022-328X(1993)450:1-2<237:TCAMOB>2.0.ZU;2-#
Abstract
The syntheses of a new tripodal ligand bis(indazol-1-yl)pyridin-2'-ylm ethane (BIPM) and of a cationic complex [Rh(BIPM)(NBD)]PF6, (NBD = 2,5 -norbornadiene) are reported. Both compounds were characterized by inf rared, H-1, and C-13 NMR spectroscopy and by single crystal X-ray anal ysis. BIPM crystallizes in the monoclinic system in space group P2(1)/ n with an alphabetaalpha helical conformation. The [Rh(BIPM)(NBD)]PF6 complex crystallizes in the monoclinic space group C/2c, the rhodium a tom being pentacoordinate with a distorted trigonal bipyramidal geomet ry.