ITA
ENG

INTRAMOLECULAR BASE COORDINATION ACCORDING TO NEED - HYLAMINOETHYL)-2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN THE COMPLEXES WITH S-BLOCK, P-BLOCK, D-BLOCK AND F-BLOCK ELEMENTS

Authors

JUTZI P DAHLHAUS J KRISTEN MO

Citation

P. Jutzi et al., INTRAMOLECULAR BASE COORDINATION ACCORDING TO NEED - HYLAMINOETHYL)-2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN THE COMPLEXES WITH S-BLOCK, P-BLOCK, D-BLOCK AND F-BLOCK ELEMENTS, Journal of organometallic chemistry, 450(1-2), 1993, pp. 1-3

Citations number

Categorie Soggetti

Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear

Journal title

Journal of organometallic chemistry → ACNP

ISSN journal

0022328X

Volume

450

Issue

1-2

Year of publication

1993

Pages

1 - 3

Database

ISI

SICI code

0022-328X(1993)450:1-2<1:IBCATN>2.0.ZU;2-N

Abstract

The synthesis of cyclopentadienyl complexes containing the polydentate C5Me4(CH2CH2NMe2) ligand is described. The compounds (C5Me4CH2CH2NMe2 )2M (M = Ca, Sm), (C5Me4CH2CH2 NMe2)AlEt2, [(C5Me4CH2CH2NMe2)M(CO)2]2 (M = Mo, Fe) and [(C5Me4CH2CH2NMe2)Fe(CO)2]+BF4- are obtained by stand ard procedures. Except for the dimeric metal carbonyls, all cyclopenta dienyl compounds are characterized by an additional intramolecular coo rdination of the nitrogen atom in the side chain.