CYCLOMETALATED DERIVATIVES OF PALLADIUM(II) AND PLATINUM(II) DERIVED FROM 6-T-BUTYL-2,2'-BIPYRIDINE

Citation
S. Stoccoro et al., CYCLOMETALATED DERIVATIVES OF PALLADIUM(II) AND PLATINUM(II) DERIVED FROM 6-T-BUTYL-2,2'-BIPYRIDINE, Journal of organometallic chemistry, 450(1-2), 1993, pp. 15-16
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
450
Issue
1-2
Year of publication
1993
Pages
15 - 16
Database
ISI
SICI code
0022-328X(1993)450:1-2<15:CDOPAP>2.0.ZU;2-4
Abstract
The synthesis of the cyclometallated derivatives [PdLCl] and [PtLCl] ( HL = 6-t-butyl-2,2'-bipyridine) is reported. The deprotonated bipyridi ne is terdentate through the two nitrogen atoms and a carbon atom of t he t-butyl substituent. The new complexes were characterized by H-1 an d C-13 NMR and FAB-MS spectra.