Gn. Matveeva et al., MESOMORPHIC PROPERTIES OF LIQUID-CRYSTALLINE COPOLYESTERS WITH ASYMMETRIC MESOGENIC GROUPS, Vysokomolekularnye soedinenia. Seria A, 35(2), 1993, pp. 186-189
Mesomorphic properties of polymers with asymmetric mesogenic groups an
d flexible methylene spacers of various lengths are studied. It was fo
und that the asymmetrical arrangement of ester groups in mesogenic fra
gments and ''head-to-head'' linking of mesogenic fragments in the macr
omolecule favor the formation of a nematic liquid-crystalline state in
the melt.