QUANTUM-CHEMICAL EVALUATION OF ENERGY PREFERENCE BETWEEN SPONTANEOUS AND INDUCED DEAGGREGATION OF METHYLLITHIUM DIMERS

Authors
YAKIMANSKII AV ERUSALIMSKII BL
Citation
Av. Yakimanskii et Bl. Erusalimskii, QUANTUM-CHEMICAL EVALUATION OF ENERGY PREFERENCE BETWEEN SPONTANEOUS AND INDUCED DEAGGREGATION OF METHYLLITHIUM DIMERS, Vysokomolekularnye soedinenia. Seria A, 35(2), 1993, pp. 212-215
Citations number
3
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
35
Issue
2
Year of publication
1993
Pages
212 - 215
Database
ISI
SICI code
0507-5475(1993)35:2<212:QEOEPB>2.0.ZU;2-J
Abstract
The MNDO method was used to evaluate the deaggregation energies of met hyllithium dimer and its complexes with benzene and acrylonitrile. The results obtained show that deaggregation of these complexes has a con siderable energy preference over deaggregation of associates which con tain no electron donor ligands. A correlation was found between these data and the electron characteristics of the compounds studied.