(3-TRIFLUOROMETHYL-BUT-3-EN-1-YNYL)TRIMETHYLSILANE AS A POTENTIALLY USEFUL CF3-CONTAINING BUILDING-BLOCK - PREPARATION AND CSF 18-CROWN-6 ETHER-CATALYZED REACTIONS WITH ALDEHYDES/

Authors
HU CM HONG F XU YY
Citation
Cm. Hu et al., (3-TRIFLUOROMETHYL-BUT-3-EN-1-YNYL)TRIMETHYLSILANE AS A POTENTIALLY USEFUL CF3-CONTAINING BUILDING-BLOCK - PREPARATION AND CSF 18-CROWN-6 ETHER-CATALYZED REACTIONS WITH ALDEHYDES/, Journal of fluorine chemistry, 63(1-2), 1993, pp. 1-3
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
63
Issue
1-2
Year of publication
1993
Pages
1 - 3
Database
ISI
SICI code
0022-1139(1993)63:1-2<1:(AAPU>2.0.ZU;2-L
Abstract
A novel CF3-containing building block, 3-trifluoromethyl-but-3-en-1-yn yl)trimethylsilane, has been prepared. It reacted readily with aldehyd es in the presence of cesium fluoride and 18-crown-6 ether to afford 2 -trifluoromethyl-1-alken-3-ynyl-5-ols.