A BOILING-POINT ESTIMATION METHOD FOR ALKANES AND PERFLUOROALKANES

Authors
VANDERPUY M
Citation
M. Vanderpuy, A BOILING-POINT ESTIMATION METHOD FOR ALKANES AND PERFLUOROALKANES, Journal of fluorine chemistry, 63(1-2), 1993, pp. 165-172
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
63
Issue
1-2
Year of publication
1993
Pages
165 - 172
Database
ISI
SICI code
0022-1139(1993)63:1-2<165:ABEMFA>2.0.ZU;2-Z
Abstract
The boiling points of non-polar liquids have been found to correlate w ell with R(m)V-1/3 where R(m) is the molar refractivity and V the mola r volume. A method for estimating the boiling points of alkanes and pe rfluoroalkanes (F-alkanes), using estimated values of R(m) and V, has been developed. The correlation coefficient was 0.996 for a data set c onsisting of 19 alkanes and 18 F-alkanes.