Second harmonic generation has been observed in electrically poled tel
lurite glasses with 80TeO2 . 10Li2O . 10 Nb2O5 and 70TeO2 . 15Li2O . 1
5Nb2O5 compositions. The poling was carried out at 200 to 300-degrees-
C for 30 min under applied dc field of 4 to 5 kV. To explain the mecha
nism generating the second-order nonlinearity in the poled tellurite g
lasses, it is proposed that strong local polarization is caused by mig
ration of lithium ions and/or periodic orientation of lone pairs of el
ectrons in the tellurium ions.