REGIOSELECTIVE PALLADIUM(0) CATALYZED AZIDATION AND AMINATION OF 1-ALKENYLCYCLOPROPYL ESTERS - A NEW ROUTE TO 2,3-METHANOAMINO ACIDS

Authors
AUFRANC P OLLIVIER J STOLLE A BREMER C ESSAYED M DEMEIJERE A SALAUN J
Citation
P. Aufranc et al., REGIOSELECTIVE PALLADIUM(0) CATALYZED AZIDATION AND AMINATION OF 1-ALKENYLCYCLOPROPYL ESTERS - A NEW ROUTE TO 2,3-METHANOAMINO ACIDS, Tetrahedron letters, 34(26), 1993, pp. 4193-4196
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
26
Year of publication
1993
Pages
4193 - 4196
Database
ISI
SICI code
0040-4039(1993)34:26<4193:RPCAAA>2.0.ZU;2-J
Abstract
Palladium (0) catalyzed azidation of 1-alkenylcyclopropyl esters provi des regioselectively 1-azido-1-alkenyl cyclopropanes, convenient precu rsors of 2,3-methanoamino acids. On the other hand, amination occurred exclusively on the less substituted allylic end, providing strained 2 -cyclopropylideneethylamine derivatives.