SYNTHESIS AND PROPERTIES OF BIS[OXYBIS(METHYLENETHIO)]TETRATHIAFULVALENE AND ITS SULFUR ANALOG - PI-DONORS FOR ORGANIC METALS

Authors
MULLER H UEBA Y
Citation
H. Muller et Y. Ueba, SYNTHESIS AND PROPERTIES OF BIS[OXYBIS(METHYLENETHIO)]TETRATHIAFULVALENE AND ITS SULFUR ANALOG - PI-DONORS FOR ORGANIC METALS, Bulletin of the Chemical Society of Japan, 66(6), 1993, pp. 1773-1777
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
66
Issue
6
Year of publication
1993
Pages
1773 - 1777
Database
ISI
SICI code
0009-2673(1993)66:6<1773:SAPOB>2.0.ZU;2-U
Abstract
Bis[oxybis(methylenethio)]tetrathiafulvalene (BOBMT- TTF) and bis[thio bis(methylenethio)]-tetrathiafulvalene (BTBMT-TTF) were synthesized in two steps starting from 1,3,4,6-tetrathiapentalene-2,5-dione. The ele ctrochemical and donor of both compounds are discussed. BOBMT-TTF form s a highly conducting charge transfer complex with TCNQ (sigma(RT) is- approximately-equal-to 10 S cm-1).