SYNTHESIS AND CHARACTERIZATION OF A SERIES OF [MO3O4(CN)9-X(H2O)X](5-X)- (X=0-3) IONS

Authors
SZKLARZEWICZ J SAMOTUS A
Citation
J. Szklarzewicz et A. Samotus, SYNTHESIS AND CHARACTERIZATION OF A SERIES OF [MO3O4(CN)9-X(H2O)X](5-X)- (X=0-3) IONS, Polyhedron, 12(12), 1993, pp. 1471-1475
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
12
Year of publication
1993
Pages
1471 - 1475
Database
ISI
SICI code
0277-5387(1993)12:12<1471:SACOAS>2.0.ZU;2-R
Abstract
Thermal or photochemical decomposition of (bpyH)3(H3O)[Mo(CN)8] . H2O in aqueous solutions gives amorphous salts with anions formulated as [ Mo3O4(CN)9-x (H2O)x](5-x)- (x = 0-3). The series of mixed-ligand compl exes was characterized by chemical analyses, UV-vis. IR and ESR spectr ometry, as well as cyclic voltammetry, thermogravimetry and electropho resis measurements. Chemical reactions, typical of molybdenum(IV) trim ers, support the formulation of salts as containing the (Mo3O4) core.