SYNTHESIS, STRUCTURE, AND THERMOLYSIS OF A 3-METHOXYCARBONYL-1,2-LAMBDA(5)-OXAPHOSPHETANE

Authors
KAWASHIMA T KATO K OKAZAKI R
Citation
T. Kawashima et al., SYNTHESIS, STRUCTURE, AND THERMOLYSIS OF A 3-METHOXYCARBONYL-1,2-LAMBDA(5)-OXAPHOSPHETANE, Angewandte Chemie, International Edition in English, 32(6), 1993, pp. 869-870
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
6
Year of publication
1993
Pages
869 - 870
Database
ISI
SICI code
0570-0833(1993)32:6<869:SSATOA>2.0.ZU;2-W
Abstract
About 22000 times faster than the decomposition of 1, 2 decomposes to form the corresponding olefin and cyclic phosphinate [Eq. (a)]; a rema rkable solvent effect is observed for the reaction of 2. Lithiation an d subsequent methoxycarbonylation of 1 provided colorless needles of 2 .